RESUMO
The solution-phase ligand-exchange strategy offers a simple pathway to prepare PbS quantum dots (QDs) and their corresponding solar cells. However, the production of high-quality PbS QDs with reduced surface trap state density for efficient PbS QD solar cells (QDSCs) still faces challenges. As the hydroxyl group (-OH) has been demonstrated to be the primary source of the surface trap states on PbS QDs in the general oleic acid method, here, we present an effective and facile strategy for reducing the surface -OH content of PbS QDs by using acetonitrile (ACN) as precipitant to wash the surface of QDs, which significantly decreases the trap state density and enables the preparation of superior PbS QDs. The resulting solar cell with an ITO/SnO2/n-PbS/p-PbS/Au structure obtained an improved photoelectric conversion efficiency (PCE) from 8.53 to 10.49% with an enhanced air storage stability, realizing a high PCE for SnO2-based PbS QDSCs.
RESUMO
For intermittent actuator faults of large-scale system, a cooperative distributed fault-tolerant model predictive control (DFTMPC) is presented. The actuator plug and play strategy is adopted in the interconnected systems with physical coupling making fault estimation and controller redesign unnecessary. The actuator plug and play process is modeled as a distributed switching model, and there a theoretical stability analysis is provided with switching form of model predictive control (MPC) cost functions. The novel cooperative distributed fault-tolerant performance index is raised in a global view for distributed model predictive control. A simulation example is taken to show the e?ectiveness of the proposed method.
